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W. Kirksey, H. G. Cutler, B. L. Doupnik, and J. C. Peckham, Science 179, 1324 (1973). 40. For a review of moniliformin and related cyclobutenediones see D. Bellus and H. P. Fisher, in "Advances in Pesticide S c i e n c e " (H. ), Part 2, p. 373. Pergamon, Oxford, 1979. 4 1 . G. Seitz, R. Schmiedel, and K. Mann, Arch. Pharm. ) 310, 991 (1979). 42. G. Seitz, R. Matusch, and K. -Ztg. 101, 557 (1977). 4 3 . T. Fukunaga, J. Am. Chem. Soc. 98, 610 (1976). 44. A. J. Fatiadi, Synthesis p. 165 (1978). 4 5 .
1 2 AH° 2 11 ± 1 r -26 ± 2 - 1 9 . 8 (pK = 3 . 0 5 ) 2 - 1 6 . 2 (pK = 1. SOy2 - 2 0 . /Spect. /Color. /Pot. /Pot. /Cond. /Pot. Method 6 12 16 15 36 36 21 21 25 Ref. A / / values are in kilocalories m o l e ; A S in calories m o l e K~ (entropy units); all data at 25°C. , calorimetric at ionic strength designated. For other abbreviations, seecfootnote b, Table 0I. (l Calorimetric AS" values calculated from pK values in parentheses. Calculated from data given in the reference. a 6 The Rhodizonic acid Croconic acid ~0 - 1 .
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